Activation Energy Equation:
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Activation energy (Ea) is the minimum amount of energy required for a chemical reaction to occur. It represents the energy barrier that must be overcome for reactants to transform into products.
The calculator uses the Arrhenius equation to determine activation energy from rate constants at two different temperatures:
Where:
Explanation: The equation relates the change in reaction rate with temperature to the activation energy of the reaction.
Details: Activation energy helps predict reaction rates, design chemical processes, and understand reaction mechanisms. It's fundamental in chemical kinetics and reaction engineering.
Tips: Enter rate constants (k1 and k2) in the same units (typically s⁻¹) and temperatures in Kelvin. All values must be positive and T1 ≠ T2.
Q1: What are typical activation energy values?
A: Most chemical reactions have Ea values between 50-250 kJ/mol, though some can be outside this range.
Q2: Why use Kelvin for temperature?
A: The equation requires absolute temperature to properly account for the temperature dependence of reaction rates.
Q3: What if my rate constants have different units?
A: The units must be identical for both rate constants as the equation uses their ratio.
Q4: Can I use Celsius temperatures?
A: No, you must convert to Kelvin first (K = °C + 273.15).
Q5: What does a negative activation energy mean?
A: Negative Ea is unusual and may indicate complex reaction mechanisms or measurement errors.