Initial Rate Equation:
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The initial rate equation describes how the rate of a chemical reaction depends on the concentration of reactants at the start of the reaction. For water, it's expressed as v₀ = k[H₂O]₀^order.
The calculator uses the initial rate equation:
Where:
Explanation: The equation shows how the initial rate depends on the rate constant, initial water concentration, and the reaction order.
Details: Calculating initial rates helps determine reaction kinetics, understand reaction mechanisms, and predict how changes in concentration affect reaction speed.
Tips: Enter the rate constant (k), initial water concentration in molarity (M), and reaction order. All values must be valid (k > 0, [H₂O]₀ > 0).
Q1: What are typical units for the rate constant?
A: Units vary with reaction order: 0th order (M/s), 1st order (1/s), 2nd order (1/M·s).
Q2: How is reaction order determined?
A: Experimentally by measuring initial rates at different concentrations.
Q3: Why focus on initial rates?
A: Initial rates avoid complications from product accumulation or reverse reactions.
Q4: Does this apply to all water reactions?
A: Only for reactions where water is a reactant and rate depends on its concentration.
Q5: What if water is the solvent?
A: For solvent reactions, water concentration is essentially constant and doesn't appear in rate law.